Publications


Auburn University

 
  1. "Adding a Second Quinol to a Redox-Responsive MRI Contrast Agent Improves its Relaxivity Response to H2O2." Yu, M.; Ward, M. B.; Franke, A.; Ambrose, S. L; Whaley, Z. L.; Bradford, T. M.; Gorden, J. D.; Beyers, R. J.; Cattley, R. C.; Ivanović-Burmazović, I.; Schwartz, D. D.; Goldsmith, C. R. Inorg. Chem., 2017, 56, 2812-2826.
  2. “Switching between Inner- and Outer-Sphere PCET Mechanisms of Small Molecule Activation: Superoxide Dismutation and Oxygen/Superoxide Reduction Reactivity Deriving from the Same Manganese Complex.” Kenkel, I.; Franke, A.; Dürr, M.; Zahl, A.; Dücker-Benfer, C.; Langer, J.; Filipović, M. R.; Yu, M.; Puchta, R.; Fiedler, S. R.; Shores, M. P.; Goldsmith, C. R., Ivanović-Burmazović, I. J. Am. Chem. Soc., 2017, 139, 1472-1484.
  3. “Aldehyde Deformylation and Catalytic C-H Activation Proceeding through a Shared Cobalt(II) Precursor.” Zhang, Q.; Bell-Taylor, A.; Bronston, F. M.; Gorden, J. D.; Goldsmith, C. R.  Inorg. Chem., 2017, 56, 773-782.
  4. "Expanding the Scope of Gallium-Catalyzed Olefin Epoxidation." Bronston, F.; Ting, S.; Zhang, Q.; Goldsmith, C. R. Polyhedron, 2016, 114, 268-272.
  5. “Synthesis and Characterization of a-Diimine Complexes of Group 13 Metals and Their Catalytic Activity Toward the Epoxidation of Alkenes.” C. A. Koellner; N. A. Piro; W. S. Kassel; C. R. Goldsmith; C. R. Graves. Inorg. Chem., 2015, 54, 7139-7141.
  6. "A Mononuclear Manganese(II) Complex Demonstrates a Strategy to Simultaneously Image and Treat Oxidative Stress." M. Yu; S. L. Ambrose; Z. L. Whaley; S. Fan; J. D. Gorden; R. J. Beyers; D. D. Schwartz; C. R. Goldsmith. J. Am. Chem. Soc., 2014, 136, 12836-12839. (open access)
  7. "Kinetic Analysis of the Formation and Decay of a Non-Heme Ferric Hydroperoxide Species Susceptible to O-O Bond Homolysis." Q. Zhang; C. R. Goldsmith. Inorg. Chem., 2014, 53, 5206-5211.
  8. "Computational Examination of the Mechanism of Alkene Epoxidation Catalyzed by Gallium(III) Complexes with N-Donor Ligands." M. L. McKee; C. R. Goldsmith. Inorg. Chem., 2014, 53, 318-326.
  9. "C-H Oxidation by H2O2 and O2 Catalyzed by a Non-Heme Iron Complex with a Sterically Encumbered Tetradentate N-Donor Ligand." Q. Zhang; J. D. Gorden; C. R. Goldsmith. Inorg. Chem., 2013, 52, 13546-13554.
  10. "Hydrocarbon Oxidation Catalyzed by Manganese and Iron Complexes with the Hexadentate Ligand N,N’-Bis(2-pyridylmethyl)-bis(ethylacetate)-1,2-ethanediamine." Q. Zhang; C. R. Goldsmith. Inorg. Chim. Acta, 2013, 406, 301-306.
  11. "Catalysis of Alkene Epoxidation by a Series of Gallium(III) Complexes with Neutral N-Donor Ligands." W. Jiang; J. D. Gorden; C. R. Goldsmith. Inorg. Chem., 2013, 52, 5814-5823. (open access)
  12. "Observation of a Ferric Hydroperoxide Complex during the Non-heme Iron Catalysed Oxidation of Alkenes and Alkanes by O2." Y. He; C. R. Goldsmith. Chem. Comm., 2012, 48, 10532-10534. 
  13. "A Magnetic Resonance Imaging Contrast Agent Capable of Detecting Hydrogen Peroxide." M. Yu; R. J. Beyers; J. D. Gorden; J. N. Cross; C. R. Goldsmith. Inorg. Chem., 2012, 51, 9153-9155. (open access)
  14. "Alkene Epoxidation Catalyzed by Manganese Complexes with Electronically Modified 1,10-Phenanthroline Ligands." C. R. Goldsmith; W. Jiang.  Inorg. Chim. Acta, 2012, 384, 340-344. 
  15. "Alkene Epoxidation with a Homogeneous Ga(III) Catalyst." W. Jiang; J. D. Gorden; C. R. Goldsmith.  Inorg. Chem., 2012, 51, 2725-2727. 
  16.  "Steric Modifications Tune the Regioselectivity of the Alkane Oxidation Catalyzed by Non-Heme Iron Complexes." Y. He; J. D. Gorden; C. R. Goldsmith.  Inorg. Chem., 2011, 50, 12651-12660.
    (open access)
  17. "Manganese(II)-Containing MRI Contrast Agent Employing a Neutral and Non-Macrocyclic Ligand." Q. Zhang; J. D. Gorden; R. J. Beyers; C. R. Goldsmith. Inorg. Chem., 2011, 50, 9365-9373. 
  18. "Hydrocarbon Chlorination Promoted by Manganese and Iron Complexes with Methylated Derivatives of Bis(2-pyridylmethyl)-1,2-ethanediamine."  C. R. Goldsmith; C. M. Coates; K. Hagan; C. A. Mitchell.  J. Mol. Catal. A, 2011, 335, 24-30.
  19. "Structural and Electrochemical Characterization of Manganese and Iron Complexes with Methylated Derivatives of Bis(2-pyridylmethyl)-1,2-ethanediamine."  C. M. Coates; K. Hagan; C. A. Mitchell, C. A.; J. D. Gorden; C. R. Goldsmith.  Dalton Trans., 2011, 40, 4048-4058.
  20. "The Halogenation of Aliphatic C-H Bonds with Peracetic Acid and Halide Salts."  Y. He; C. R. Goldsmith.  SynLett, 2010, 21, 1377-1380.
  21. "Synthesis and Characterization of an Asymmetric, Linear, Trinuclear Manganese(II) Complex."  C. M. Coates; S. R. Fiedler; T. L. McCullough; T. E. Albrecht-Schmitt; M. P. Shores; C. R. Goldsmith.  Inorg. Chem., 2010, 49, 1481-1486.
  22. "Assessing the Impact of Inductive Electronic Effects on the Metrical Parameters and Reactivity of a Series of Ferrous Complexes."  C. M. Coates; A.-G. D. Nelson; C. R. Goldsmith.  Inorg. Chim. Acta, 2010, 363, 199-204.
  23. "The Influence of Ligand Electronics on the Metrical Parameters and Redox Potentials of a Series of Manganese(II) Compounds."  C. M. Coates; A.-G. D. Nelson; C. R. Goldsmith.  Inorg. Chim. Acta, 2009, 362, 4797-4803.


Massachusetts Institute of Technology (Postdoctoral Work)

 
  1. "Two-Photon Imaging of Zn2+ Dynamics in Mossy Fiber Boutons of Adult Hippocampal Slices." M. Khan; C. R. Goldsmith; Z. Huang; J. Georgiou; T. T. Luyben; J. C. Roder; S. J. Lippard; K. Okamoto. Proc. Natl. Acad. Sci. U.S.A., 2014, 111, 6786-6791.
  2. "Analogs of Zinpyr-1 Provide Insight into the Mechanism of Zinc Sensing."  C. R. Goldsmith; S. J. Lippard.  Inorg. Chem., 2006, 45, 6474-6478.
  3. "Selective Labeling of Extracellular Proteins Containing Polyhistidine Sequences by a Fluorescein-Nitrilotriacetic Acid Conjugate."  C. R. Goldsmith; J. Jaworski; M. Sheng; S. J. Lippard.  J. Am. Chem. Soc., 2006, 128, 418-419.
  4. "6-Methyl for Pyridyl Substitution Tunes the Properties of Fluorescent Zinc Sensors of the Zinpyr Family."  C. R. Goldsmith; S. J. Lippard.  Inorg. Chem., 2006, 45, 555-561. 


Stanford University (Graduate Work)

 
  1. "Hydrogen Atom Abstraction by a Mononuclear Ferric Hydroxide Complex:  Insights into the Reactivity of Lipoxygenase."  C. R. Goldsmith; T. D. P. Stack.  Inorg. Chem., 2006, 45, 6048-6055. 
  2. "C-H Activation by a Mononuclear Manganese(III) Hydroxide Complex:  Synthesis and Characterization of a Manganese-Lipoxygenase Mimic?"  C. R. Goldsmith; A. P. Cole; T. D. P. Stack.  J. Am. Chem. Soc., 2005, 127, 9904-9912.
  3. "X-ray Absorption Spectroscopic Investigation of the Spin-Transition Character in a series of Single-Site Perturbed Iron(II) Complexes."  D. Jackson Rudd; C. R. Goldsmith; A. P. Cole; T. D. P. Stack; K. O. Hodgson; B. Hedman.  Inorg. Chem., 2005, 44, 1221-1229. 
  4. "A Spectrochemical Walk:  Single-Site Perturbation within a Series of Six-Coordinate Ferrous Complexes."  C. R. Goldsmith; R. T. Jonas, T. D. P. Stack.  Inorg. Chem., 2002, 41, 4642-4652.
  5. "A Periodic Walk:  A Series of First-Row Transition Metal Complexes with the Pentadentate Ligand PY5."  R. J. M. Klein-Gebbink; R. T. Jonas; C. R. Goldsmith; T. D. P. Stack.  Inorg. Chem., 2002, 41, 4633-4641.
  6.  "C-H Bond Activation by a Ferric Methoxide Complex:  Modeling the Rate-Determining Step in the Mechanism of Lipoxygenase."  C. R. Goldsmith; R. T. Jonas; T. D. P. Stack.  J. Am. Chem. Soc., 2002, 124, 83-96.


Harvard University (Undergraduate Work)


  1. "Synthesis, Structures, and Reactivity of Bis(dithiolene)molybdenum(IV,VI) Complexes Related to the Active Sites of Molybdoenzymes."  J. P. Donahue.; C. R. Goldsmith; U. Nadiminti; R. H. Holm.  J.Am. Chem. Soc., 1998, 120, 12869-12881.