CH1010 Course Outline

 

Text: "General, Organic, and Biochemistry" By I. Blei and G. Odian, W. H. Freeman and Co., New York, 2000.

 

I. Introduction

A. Chemistry in the modern world, pp.1-10.

B. Measurement and calculation in chemistry

1. Significant figures and scientific notation, pp.12-15.

2. The metric system, pp.10-12.

3. Scientific calculations, pp.15-33.

C. Problems. In chapter: 1.1-1.20. pp.34-36: 1.1-1.44.

II. Atomic Structure

A. Dalton's atomic theory and atomic masses, pp.37-41.

B. The structure of the atom, pp.41-44.

C. The periodic table, pp.44-48.

D. The electronic structure of the atom, pp.48-62.

E. Problems. In chapter: 2.1-2.14. Pp.63-64: 2.1-2.14, 2.17-2.24, 2.26-2.56, 2.59-2.62.

 

III. Molecules and Chemical Bonding

A. Ionic bonding, pp.65-76.

B. Covalent bonding

1. Lewis structures for simple molecules, pp.76-84, 286-294.

2. Polar covalent bonds, pp.84-86.

3. Hydrogen bonding and other attractive forces between molecules, pp. 151-157.

4. Three dimensional molecular structure, pp.86-91, 294-302.

5. Naming alkanes, pp.302-307.

C. Problems. In chapters: 3.1-3.14, 6.1-6.2, 11.1-11.7. pp.92-93: 3.1-3.46, 3.51-3.53. p.171: 6.17-6.18. pp.324-326: 11.2-11.18, 11.20-11.24.

 

IV. Chemical Calculations

A. Chemical formulas and molecular weights, pp.94-97.

B. The mole concept, pp.97-100.

1. Determining empirical and molecular formulas, pp.100-104.

C. Balancing equations, pp.104-111.

D. Stoichiometry problems, pp.111-117.

E. Problems. In chapter: 4.1-4.17. pp.118-119: 4.1-4.55.

 

V. The Properties of Gasses

A. Gas pressure, pp.120-124.

B. The gas laws, pp.124-139.

1. Dalton's law of partial pressures, pp.139-140.

C. Problems. In chapter: 5.1-5.13. pp. 145-146: 5.1-5.39.

 

VI. Interactions Between Molecules

A. States of matter, pp.148-151.

B. Intermolecular forces, pp.151-161.

1. Hydrogen bonding, pp.153-155, 376-381, 603-604, 628-630.

C. Vapor pressure and vaporization, pp.161-167.

D. The structure of solids, pp.167-169.

E. Problems. In chapter: 6.1-6.9, 13.6, 21.4. pp.170-171: 6.1-6.22, 6.25-6.30, 6.52-6.59.

 

VII. The Properties of Solutions

A. Ways of expressing concentrations of solutions, pp.173-186.

B. Solubility, pp.186-190.

C. Osmosis and membranes, pp.190-199.

D. Problems. In chapter: 7.1-7.14. pp. 199-201: 7.1-7.45, 7.50-7.71.

 

VIII. Chemical Reactions

A. Chemical kinetics and reaction rates, pp.201-204.

1. Activation energies and energy diagrams, pp.204-208.

B. Catalysis, pp.208-211, 341-342, 669-671.

C. Chemical equilibrium, pp.211-220.

D. The interplay between kinetics and thermodynamics, class notes.

E. Problems. In chapter: 8.1-8.8. pp.220-222: 8.1-8.7,8.9-8.38.

 

IX. Acid-Base Chemistry

A. Properties of acids and bases, pp.223-226.

B. Strong acids and bases, pp.226-228.

C. The pH scale, pp.228-233.

D. Weak acids and bases, pp.233-238.

1. Acid and base dissociation constants, pp.233-243.

E. Buffers, pp.243-249.

F. Titration and normality, pp. 249-254.

G. Problems. In chapter: 9.1-9.17. pp.255-257: 9.1-9.39, 9.45-9.58.

 

X. Chemical and Biological Effects of Nuclear Radiation

A. Radioactive emissions and half-lives, pp.258-265.

1. Types of radiation, pp. 265-267.

2. Radioactive dating, p. 267.

B. Biomedical applications and hazards of radiation, pp.267-270, 275-279.

1. Radiation and the ozone layer, p.269 and class notes.

C. Nuclear energy, pp.279-282.

D. Problems. In chapter: 10.1-10.6. pp.283-284: 10.1-10.8,10.13-10.14,10.43-10.44.

 

XI. Saturated Hydrocarbons (Alkanes)

A. Overview of organic chemistry, pp286-293.

B. Alkanes

1. Structure, pp.293-302.

2. Nomenclature, pp.302-307.

C. Cycloalkanes, pp.308-313.

1. Stereoisomerism in cycloalkanes, pp.310-313.

2. Conformation in cycloalkanes, p.311.

D. Physical properties of saturated hydrocarbons, pp.313-316.

E. Reactions of saturated hydrocarbons.

1. Combustion, pp.316-320.

a) Global warming and hydrocarbon combustion, p.319 and class notes.

2. Halogenation, pp.320-323.

F. Problems. In chapter: 11.1-11.16. pp.324-328: 11.1-11.52, 11.56-11.59.

 

XII. Unsaturated Hydrocarbons

A. Alkenes

1. Structure, pp.329-336.

2. Nomenclature, pp.336-337.

3. Stereoisomerism in alkenes (cis-trans isomers), pp.337-341.

4. Addition reactions of alkenes, pp.341-349.

a) Addition of symmetric reagents: Hydrogenation and halogenation, pp.341-343.

b) Addition of unsymmetric reagents: Water and acids, pp.343-347.

c) Addition polymerization, pp.346-349.

5. Oxidation of alkenes, pp.349-351.

B. Alkynes, p. 351.

C. Aromatic compounds

1. Structure and bonding, pp. 352-356.

2. Nomenclature, pp.254-257.

3. Electrophilic aromatic substitution reactions, pp.357-359.

4. Aromatic compounds other than benzene, p.360, 469, and class notes.

D. Problems. In Chapter: 12.1-12.13. pp.362-368. 12.1-12.22,12.25-12.28, 12.31-12.43, 12.45-12.46, 12.48-12.56, 12.61-12.68.

XIII. Alcohols, Phenols, Ethers, and their Sulfur Analogs

A. Alcohols

1. Structure, pp.369-373.

2. Nomenclature of alcohols, pp.373-375

3. Physical properties, pp.375-381.

4. Reactions

a) Acidity and basicity, p.381.

b) Dehydration to alkenes, pp.381-384.

c) Oxidation, pp.384-388.

B. Phenols

1. Structure and nomenclature, pp.388-391.

C. Ethers

1. Structure and nomenclature, pp. 391-394.

2. Formation of ethers by dehydration of alcohols, pp.394-395.

D. Sulfur analogs, pp.395-396.

E. Problems. In chapter: 13.1-13.17. pp. 398-402: 13.1-13.8, 13.15-13.18, 13.21-13.24, 13.27-13.28, 31.31-13.41, 13.46-13.50, 13.55-13.63.

Back to Survey of Chemistry